1)Construct line AFE to E' where AE' is parallel to CD. 2)Join DE'. 3)Add a point E'' on FE
No matter which point E' or E'' are, angle FE'D + angle E'DF or angle FE''D + angle E''DF = 144 = angle AFD (ext angle of triangle) and there is no contradiction with the given information. Therefore CF may not parallel to DE.